How much do coulombic interactions stabilize a mesophase? Ion pair and non-ionic binary isosteric derivatives of monocarbaborates and carboranes

作者：Jankowiak Aleksandra; Sivaramamoorthy Ajan; Pociecha Damian; Kaszynski Piotr^*

来源：RSC Advances, 2014, 4(96): 53907-53914.

DOI：10.1039/c4ra06502f

Replacement of the B- atom in the monocarbaborate anion, 1[10] or 1[12], and the N+ atom in the pyridinium cation [Pyr] of a liquid crystalline ion pair with C atoms leads to an isoelectronic and isosteric non-ionic binary liquid crystalline mixture of carborane (2[10] or 2[12]) and benzene ([Ph]) derivatives lacking coulombic interactions. A comparison of mesogenic properties of ion pairs, 1[10] c-[Pyr] c and 1 [12] c-[Pyr] c, with their analogous non-ionic mixtures, 2[10] c-[Ph] c and 2[12] c-[Ph] c, shows a 181 K higher clearing temperature, T-c, for the ion pair. This corresponds to a DFT-calculated difference in association energy Delta Delta H-a = 24.5 kcal mol(-1) in a typical dielectric medium (epsilon = 2.5). Pure compounds and binary mixtures were characterized using thermal, optical, and XRD methods.

• 出版日期2014