Directed Synthesis of Crystalline Plutonium(III) and (IV) Oxalates: Accessing Redox-Controlled Separations in Acidic Solutions

作者：Runde Wolfgang^*; Brodnax Lia F; Goff George; Bean Amanda C; Scott Brian L

来源：Inorganic Chemistry, 2009, 48(13): 5967-5972.

DOI：10.1021/ic900344u

Single crystals of hydrated oxalates of Pu(III), Pu(2)(C(2)O(4))(3)(H(2)O)6 center dot 3H(2)O and Pu(IV), KPu(C(2)O(4))(2)-(OH)center dot 2.5H(2)O, were synthesized under moderate hydrothermal conditions and characterized by single crystal X-ray diffraction studies. These compounds are the first plutonium (III) or (IV) oxalate compounds to be structurally characterized via single crystal X-ray diffraction studies.

• 出版日期2009-7-6