摘要

The crystal structures of N-pentafluorobenzyl aniline derivatives are controlled by versatile aromatic-aromatic interactions between the electron deficient and electron rich aromatics; the parent compound (1) possesses an L shape while protonation (2-5) induces a conformational change resulting in a planar arrangement of molecules which pack in layer type structures with different molecular orientations.

  • 出版日期2010