Approaching a stable, green twisted heteroacene through "clean reaction'' strategy

作者:Li Gang; Duong Hieu M; Zhang Zhonghan; Xiao Jinchong; Liu Lei; Zhao Yanli; Zhang Hua; Huo Fengwei; Li Shuzhou; Ma Jan; Wudl Fred*; Zhang Qichun
来源:Chemical Communications, 2012, 48(48): 5974-5976.
DOI:10.1039/c2cc32048g

摘要

A new, longest, stable, green twisted heteroacene 2-methyl-1,4,6,13-tetraphenyl-7:8,11:12-bisbenzo-anthro[g]isoquinolin-3(2H)-one (3) was synthesized by employing a "clean reaction'' strategy based on thermally eliminating lactam bridges. Calculation shows that the HOMO-LUMO bandgap is in good agreement with experimental data.

  • 出版日期2012
  • 单位南阳理工学院