NHC-Pd(II)-Im (NHC = N-heterocyclic carbene; Im=1-methylimidazole) complexes as efficient catalysts for Suzuki-Miyaura coupling reactions of aryl chlorides

作者：Tang Yi Qiang; Lu Jian Mei; Shao Li Xiong^*

来源：Journal of Organometallic Chemistry, 2011, 696(23): 3741-3744.

DOI：10.1016/j.jorganchem.2011.08.042

• N-heterocyclic carbene
• Palladium complex
• Imidazole
• Suzuki-Miyaura coupling reaction
• Synthetic method

A new type of well-defined N-heterocyclic carbene (NHC)-palladium chloride-imidazole complexes derived from IPr(center dot)HCl or IMes(center dot)HCl, PdCl(2) and 1-methylimidazole exhibits high catalytic activity in the room-temperature Suzuki-Miyaura coupling reactions of aryl or heteroaryl chlorides. Moreover, the large-scale (20.0 mmol) couplings in the presence of 0.01 mol% catalyst loading can also give the corresponding coupling products in high yields.

• 出版日期2011-11-15
• 单位温州大学