摘要

The distribution (or partition) coefficient (K-d) is an applicable parameter for modeling contaminant and radionuclide transport as well as risk analysis. Selection of this parameter may cause significant error in predicting the impacts of contaminant migration or site-remediation options. In this regards, various models were presented to predict K-d values for different contaminants specially heavy metals and radionuclides. In this study, artificial neural network (ANN) is used to present simplified model for predicting K-d of nickel. The main objective is to develop a more accurate model with a minimal number of parameters, which can be determined experimentally or select by review of different studies. In addition, the effects of training as well as the type of the network are considered. The K-d values of Ni is strongly dependent on pH of the soil and mathematical relationships were presented between pH and K-d of nickel recently. In this study, the same database of these presented models was used to verify that neural network may be more useful tools for predicting of K-d. Two different types of ANN, multilayer perceptron and redial basis function, were used to investigate the effect of the network geometry on the results. In addition, each network was trained by 80 and 90% of the data and tested for 20 and 10% of the rest data. Then the results of the networks compared with the results of the mathematical models. Although the networks trained by 80 and 90% of the data the results show that all the networks predict with higher accuracy relative to mathematical models which were derived by 100% of data. More training of a network increases the accuracy of the network. Multilayer perceptron network used in this study predicts better than redial basis function network.

  • 出版日期2013-1

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