A hydrogenase model system based on the sequence of cytochrome c: photochemical hydrogen evolution in aqueous media

作者：Sano Yohei; Onoda Akira; Hayashi Takashi^*

来源：Chemical Communications, 2011, 47(29): 8229-8231.

DOI：10.1039/c1cc11157d

The diiron carbonyl cluster is held by a native CXXC motif, which includes Cys14 and Cys17, in the cytochrome c sequence. It is found that the diiron carbonyl complex works well as a catalyst for H(2) evolution. It has a TON of similar to 80 over 2 h at pH 4.7 in the presence of a Ru-photosensitizer and ascorbate as a sacrificial reagent in aqueous media.

• 出版日期2011