A facile strategy for rapid preparation of graphene spongy balls

作者:Wan, Shu; Bi, Hengchang; Xie, Xiao; Su, Shi; Du, Kai; Jia, Haiyang; Xu, Tao; He, Longbing; Yin, Kuibo; Sun, Litao*
来源:Scientific Reports, 2016, 6(1): 32746.
DOI:10.1038/srep32746

摘要

Porous three dimensional (3D) graphene macrostructures have demonstrated the potential in versatile applications in recent years, including energy storage, sensors, and environment protection, etc. However, great research attention has been focused on the optimization of the structure and properties of graphene-based materials. Comparatively, there are less reports on how to shape 3D graphene macrostructures rapidly and effortlessly, which is critical for mass production in industry. Here, we introduce a facile and efficient method, low temperature frying to form graphene-based spongy balls in liquid nitrogen with a yield of similar to 400 balls min(-1). Moreover, the fabrication process can be easily accelerated by using multi pipettes working at the same time. The graphene spongy balls show energy storage with a specific capacitance of 124 F g(-1) and oil adsorbing with a capacity of 105.4 times its own weight. This strategy can be a feasible approach to overcome the low efficiency in production and speed up the development of porous 3D graphene-based macrostructures in industrial applications.