Sunlight-induced decarboxylative radical addition of carboxylic acids to electron-deficient alkenes using a millitube reactor

作者：Yoshimi Yasuharu^*; Nishio Akinori; Hayashi Masae; Morita Toshio

来源：Journal of Photochemistry and Photobiology A: Chemistry , 2016, 331: 17-21.

DOI：10.1016/j.jphotochem.2016.03.012

• Sunlight-induced
• Decarboxylative radical addition
• Electron-deficient alkene
• Millitube reactor

The use of a fluorinated ethylene propylene (FEP) millitube reactor significantly improved the efficiency of the photoinduced decarboxylative radical addition of aliphatic carboxylic acids to electron-deficient alkenes, producing the corresponding gamma-amino acid derivative and macrocyclic lactone. These sunlight-induced photoreactions were achieved using a millitube reactor, even though the photosensitizer used in this system absorbs only UV light.

• 出版日期2016-12-1