Partitioning of the quinary reciprocal system Li,KaEuro-F,Cl,Br,MoO4 into simplexes and the investigation of its partitioning and stable elements

作者：Garkushin I K^*; Demina M A; Bekhtereva E M

来源：Russian Journal of Inorganic Chemistry, 2014, 59(3): 259-267.

DOI：10.1134/S003602361403005X

The quinary reciprocal system Li,KaEuro-F,Cl,Br,MoO4 was partitioned into simplexes using graph theory. A tree of phases of the system was constructed, and stable elements were identified. The chemical interaction in the system Li,KaEuro-F,Cl,Br,MoO4 was described by the ion balance method. The stable tetrahedra LiF-KCl-KBr-K2MoO4, LiF-KCl-KBr-LiKMoO4, and LiF-Li2MoO4-KCl-KBr and the united stable pentatope LiF-KF-KCl-KBr-K2MoO4 were studied by differential thermal analysis, and phase states in the studied simplexes were determined. The compositions of crystallizing phases in the bulk of the studied tetrahedra and pentatope were confirmed by X-ray powder diffraction analysis.

• 出版日期2014-3