A metal-organic polyhedron based on dibenzothiophene ligand: Gas adsorption and reductive properties

作者：Ma, Sha; Niu, Yanfei; Zhao, Xiaoli^*; Duan, Zhiming^*

来源：Inorganic Chemistry Communications, 2016, 70: 10-13.

DOI：10.1016/j.inoche.2016.05.009

• Metal-organic polyhedra
• Dibenzothiophene
• Gas sorption
• Reduction
• TCNQ

A new metal-organic polyhedron Cu-MOP with octahedral geometry was constructed by 2,8-dibenzothiophenedicarboxylic acid and dicopper paddlewheel. Cu-MOP exhibited H-2 and CO2 sorption behavior. Furthermore, Cu-MOP revealed reductive properties towards TCNQ, DDQ, CR and MB due to the electron-donating nature of DBT ligand.

• 出版日期2016-8
• 单位华东师范大学; 上海大学