Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation

作者：Martins L M D R S^*; Ribeiro A P C; Carabineiro S A C; Figueiredo J L; Pombeiro A J L

来源：Dalton Transactions, 2016, 45(16): 6816-6819.

DOI：10.1039/c6dt00514d

The highly efficient eco-friendly synthesis of ketones (yields over 99%) from secondary alcohols is achieved by combination of [FeCl2{eta(3)-HC(pz)(3)}] (pz = pyrazol-1-yl) supported on functionalized multi-walled carbon nanotubes and microwave irradiation, in a solvent-free medium. The carbon homoscorpionate iron(II) complex is the first one of this class to be used as catalyst for the oxidation of alcohols.

• 出版日期2016