Assessing chiral self-recognition using chiral stationary phases

作者：Lee Wonjae; Snyder Seth E; Volkers Phillip I; Pirkle William H; Engebretson David A; Boulanger William A; Lin Huei Shian; Huang Bin Syuan; Carey James R^*

来源：Tetrahedron, 2011, 67(37): 7143-7147.

DOI：10.1016/j.tet.2011.06.103

• Molecular recognition
• Homochiral
• Chiral stationary phases
• Self-assembly
• pi-pi Interaction

Chiral stationary phases were synthesized and their ability to separate racemic precursors from which they were derived was assessed. Taken in conjunction with homochiral recognition previously observed in the solid state, the results of this study reveal that a geometrically controlling pi-pi interaction has a profound influence on molecular recognition.

• 出版日期2011-9-16