A triPEG-boron based electrolyte membrane for wide temperature lithium ion batteries

作者：Xu, Junyi; Li, Jie; Zhu, Yuewu; Zhu, Kai; Liu, Yexiang; Liu, Jin^*

来源：RSC Advances, 2016, 6(24): 20343-20348.

DOI：10.1039/c6ra02865a

• SOLID POLYMER ELECTROLYTES
• POLY(ETHYLENE OXIDE)
• ANION RECEPTOR
• CONDUCTIVITY
• ESTER
• LAYER
• NMR
• PERFORMANCE
• ALUMINA
• LICLO4

A triPEG-boron based solid polymer electrolyte (SPE) membrane is fabricated for all-solid-state lithium ion batteries. With an ether oxygen (EO) : LiN(SO2CF3)(2) (LiTFSI) molar ratio of 25 : 1, this electrolyte membrane has ionic conductivities of 2.95 x 10(-5) S cm(-1) and 1.28 x 10(-3) S cm(-1), and electrochemical decomposition potentials of 5.23 V and 4.88 V, respectively at 25 degrees C and 120 degrees C. The all-solid-state LiFePO4/SPE/Li batteries show high cycling performance in the temperature range of 25-140 degrees C. At 25 degrees C and 0.3C, a discharge capacity of 84 mA h g(-1) is obtained at the 200th charge-discharge cycle with approximately 100% coulombic efficiency. The batteries also work well at 140 degrees C and 3C, delivering a discharge capacity of 146 mA h g(-1) initially and 113 mA h g(-1) after 200 cycles. These results show that this kind of all-solid-state lithium ion battery has a wider working temperature range than conventional liquid electrolyte lithium ion batteries, indicating their suitability for use in fields with high safety requirements.

• 出版日期2016
• 单位中南大学