DPDS-DPS in situ transformation at room temperature via a 1,2-nucleophilic addition mechanism

作者：De la Pinta Noelia^*; Caballero Ana B; Madariaga Gotzon; Ezpeleta Jose M; Rodriguez Dieguez Antonio; Salas Juan M; Cortes Roberto

来源：CrystEngComm, 2014, 16(36): 8322-8326.

DOI：10.1039/c4ce00781f

A cleavage-reorganization reaction at room temperature has been detected in three metal organic coordination compounds synthesized from a DPDS [di(4-pyridyl)disulphide] ligand: Mn(NCS)(2)(DPS)(4) (1), [Fe(NCS)(2)(DPS)(2)]center dot 2H(2)O (2) and Zn(NCO)(2)(DPS) (3), [DPS = di(4-pyridyl)sulphide]. The in situ reorganization process is explained by a 1,2-nucleophilic addition mechanism.

• 出版日期2014-9-28