A 3D Calcium Spirobifluorene Metal-Organic Framework: Single-Crystal-to-Single-Crystal Transformation and Toluene Detection by a Quartz Crystal Microbalance Sensor

作者：Fang, Xueting; Wang, Luyu; He, Xiang; Xu, Jiaqiang^*; Duan, Zhiming^*

来源：Inorganic Chemistry, 2018, 57(4): 1689-1692.

DOI：10.1021/acs.inorgchem.7b02671

• ADSORPTION
• REMOVAL
• CAPTURE
• ACID

A new 3D metal organic framework Ca-SBF based on a zigzag-shaped tetranuclear calcium oxocluster and 9,9'-spirobi[9H-fluorene]-2,2',7,7'-tetracar-boxylic acid was obtained and exhibited flu topology. Ca-SBF underwent a single-crystal-to-single-crystal transformation to form Ca-SBF-1 with a slight structure shrinkage. Activated Ca-SBF showed permanent porosity and CO2 adsorption properties. A Ca-SBF-modified quartz crystal microbalance sensor demonstrated selective response to toluene vapor.

• 出版日期2018-2-19
• 单位上海大学