Alkali metal-mediated dehydrocoupling of Me2NH center dot BH3

作者：Bellham Peter; Hill Michael S^*; Kociok Koehn Gabriele

来源：Dalton Transactions, 2015, 44(27): 12078-12081.

DOI：10.1039/c5dt00178a

Bis(trimethylsilyl) amide derivatives of the group 1 elements (Li, Na, K) are competent pre-catalysts for the dehydrocoupling of Me2NH center dot BH3 via the formation of intermediates containing [H3BNMe2BH2Me2N](-) anions.

• 出版日期2015