摘要
The 3D coordination polymer {[Cd(dpa)(bpe)]center dot 2H(2)O}n (1)[H(2)dpa = 2,4-biphenyl dicarboxylic acid and bpe = 1,2-bis(4-pyridyl)ethane] was prepared by hydrothermal synthesis and characterized by single X-ray diffraction, FTIR spectra and element analysis. The title complex 1 exhibits an unusual three-dimensional framework with (6,6)-connected (3(2).4(2).5(2).6(8).8) (3(4).4(4).5(4).6(3)) topology. Furthermore, the solid-state photoluminescence property of 1 is investigated at room temperature.