Application of iridium pincer complexes in hydrogen isotope exchange reactions

作者:Traff Annika; Nilsson Goran N; Szabo Kalman J*; Eriksson Ludvig
来源:Journal of Organometallic Chemistry, 2007, 692(25): 5529-5531.
DOI:10.1016/j.jorganchem.2007.09.009

摘要

Iridium pincer complex catalyzed hydrogen to deuterium exchange could be achieved using aromatic and heteroaromatic substrates. The reactions proceed under mild conditions and with high regioselectivity. The efficiency of the hydrogen isotope exchange reaction depends on the electronic properties of the pincer complex catalyst.

  • 出版日期2007-12-1