Diaquabis[5-(pyrimidin-2-yl)tetrazolato]-manganese(II)

作者:Liu Ju Tao*; Fan Sheng Di
来源:Acta Crystallographica Section E-Structure Reports Online, 2007, 63: M1628-U523.
DOI:10.1107/S1600536807021885

摘要

The title complex, [Mn(C5H3N6)(2)(H2O)(2)], possesses a crystallographically imposed center of symmetry occupied by an Mn-II ion, which is coordinated by four N atoms from two 5-(pyrimidin-2-yl) tetrazolate ligands [Mn-N = 2.2066 (13) and 2.2731 (15) angstrom] and two water molecules [Mn-O = 2.1868 (14) angstrom] in a distorted octahedral geometry. In the crystal structure, intermolecular O-H center dot center dot center dot N hydrogen bonds link the complexes into two-dimensional sheets parallel to the bc plane.