Magnetic canting or not? Two isomorphous 3D Co-II and Ni-II coordination polymers with the rare non-interpenetrated (10,3)-d topological network, showing spin-canted antiferromagnetism only in the Co-II system

作者：Li Jian Rong; Yu Qun; Tao Ying; Bu Xian He^*; Ribas Joan; Batten Stuart R

来源：Chemical communications, 2007, (22): 2290-2292.

DOI：10.1039/b700569e

The in situ solvothermal reaction of 3,4-dicyano-1,2,5-thiadiazole with MCl2 (M = Co, Ni) and NaOH afforded two isomorphous complexes, [M-2(L)(2)(H2O)(2)](n) (L = 2,1,3-thiadiazole-4,5-dicarboxylate), which exhibit a rare non-interpenetrated (10,3)-d (utp) network topology and interesting magnetic behaviors: spin-canted antiferromagnetism for the Co-II complex, but simple antiferromagnetic coupling for the Ni-II.

• 出版日期2007-6-14
• 单位南开大学