Adsorption of equal mass fraction near an azeotropic mixture of pentafluoroethane and 1,1,1-trifluoroethane on activated carbon

作者:Saha Bidyut B; El Sharkawy Ibrahim I; Habib Khairul; Koyama Shigeru; Srinivasan Kandadai*
来源:Journal of Chemical and Engineering Data, 2008, 53(8): 1872-1876.
DOI:10.1021/je800204p

摘要

This paper presents adsorption isotherms for R-507A, which is a near azeotropic mixture of R-125 (pentafluoroethane) and R-143a (1, 1, 1-trifluoroethane) in equal mass fractions, on a Maxsorb III specimen of activated carbon in the temperature range of about (5 to 70) degrees C and pressure up to 15 bar. The data were obtained using the desorption method to an estimated precision of 5 % and fitted to three isotherm equations, namely, Dubinin-Astakhov, Langmuir, and Toth. The adsorption parameters were determined. Some peculiarities in isosteric heating behavior were observed.

  • 出版日期2008-8