科研之友
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摘要
A hierarchical porous Li2FeSiO4/C composite was prepared using an in situ template synthesis by tetraconstituent co-assembly of resols, nitrates, silica oligomers, and a triblock copolymer surfactant. The structural and electrochemical characterizations revealed that the Li2FeSiO4/C composite has a hierarchical micro-, meso- and macro-porous structure, in which macrosized pores provide abundant electrolyte channels for fast ionic transport, while the microporous network offers large accessible electrochemically active areas for the Li insertion reaction. The Li2FeSiO4/C composite demonstrates a very high capacity of 254 mA h g(-1) at room temperature with excellent cycling stability and rate capability, corresponding to 77.5% utilization of its theoretical 2 Li storage capacity. The results from this study suggest a feasible approach to improve dramatically the electrochemical utilization and cyclability of the kinetically sluggish intercalation compounds by creating an electrochemically favorable porous structure and the synthetic strategy described in this work may be extended to fabricate other types of porous multifunctional materials for energy storage, catalysis and other applications.
- 出版日期2013
- 单位中国人民解放军国防科学技术大学; 武汉大学
