A stable, pillar-layer metal-organic framework containing uncoordinated carboxyl groups for separation of transition metal ions

作者：Meng, Xing; Zhong, Rong-Lin; Song, Xue-Zhi; Song, Shu-Yan^*; Hao, Zhao-Min; Zhu, Min; Zhaoa, Shu-Na; Zhang, Hong-Jie

来源：Chemical communications, 2014, 50(48): 6406-6408.

DOI：10.1039/c4cc00553h

• SELECTIVE SEPARATION
• HYDROGEN ADSORPTION
• CAPTURE
• STORAGE
• WATER
• STABILITY

A 3D pillar-layer framework (1) with uncoordinated carboxyl groups exhibits exceptional stability. It can effectively and selectively adsorb Cu2+ ions and has been applied as a chromatographic column for separating Cu2+/Co2+ ions.

• 出版日期2014
• 单位中国科学院长春应用化学研究所; 东北师范大学; 稀土资源利用国家重点实验室; 中国科学院大学