A novel two-dimensional layer compound built up by hexapolyoxotungstates and coordinated sodium chains

作者：Jiang, XY; Xiao, LR; Zhang, QZ; Yang, WB; Lu, CZ^*

来源：Chinese Journal of Structural Chemistry, 2005, 24(5): 581-585.

• crystal structure
• hexapolyoxotungstate
• building blocks
• 2D-layer
• coordinated Na

The 2D-layer compound ([Na-2(C8H12N2O3)(4)(C2H6SO)(4)(W6O19)](n) 1, M-r = 2133.98) synthesized by the reaction of sodium tungstate and barbitone sodium in the solution of DMSO and water has been characterized by IR and Raman spectra, elemental analysis and TGA. X-ray diffraction analysis indicates that Compound 1 crystallizes in the monoclinic system, space group C2/c with a 14.8026(4), b = 17.3012(3), c = 19.6379(5) A, beta = 98.6300 degrees, V = 4972.4(2) angstrom(3), Z = 4, F(000) 3928, D-c = 2.851 and mu = 14.101 mm(-1). 1 has a two-dimensional layer structure with hexapolyoxotungstate building blocks and coordinated sodium chains.

• 出版日期2005
• 单位中国科学院福建物质结构研究所; 福建师范大学; 福建工程学院; 结构化学国家重点实验室