A ruthenium(II) hydride carbonyl complex with 4-phenylpyrimidine as co-ligand

作者：Malecki J G^*; Maron A

来源：Transition Metal Chemistry, 2012, 37(8): 727-734.

DOI：10.1007/s11243-012-9644-x

The reaction of [RuHCl(CO)(PPh3)(3)] with 4-phenylpyrimidine gave a new ruthenium(II) complex, namely [RuHCl(CO)(PPh3)(2)(pyrim-4-Ph)]. The complex has been studied by IR and UV-vis spectroscopy and by X-ray crystallography. The molecular orbitals of the complex have been calculated by density functional theory. The spin-allowed singlet-singlet electronic transitions of the complex have been calculated by time-dependent DFT, and the UV-vis spectrum of the compound has been discussed on this basis. The emission properties of the complex were also studied.

• 出版日期2012-11