Design and Synthesis of Diphosphine Ligands Bearing an Osmium(II) Bis(terpyridyl) Moiety as a Light-Harvesting Unit: Application to Photocatalytic Production of Dihydrogen

作者：Miyake Yoshihiro; Nakajima Kazunari; Sasaki Kouitsu; Saito Ryuichi; Nakanishi Haruyuki; Nishibayashi Yoshiaki^*

来源：Organometallics, 2009, 28(17): 5240-5243.

DOI：10.1021/om900489d

We have designed and prepared novel diphosphine ligands bearing an OS(tpy)(2)(2 ) moiety as a light-harvesting unit and have found that these diphosphine ligands coordinate to the rhodium atom in a bidentate manner. The rhodium complexes including diphosphine ligands bearing an OS(tpy)(2)(2 ) moiety have been revealed to work as an effective photocatalyst for the production of dihydrogen.

• 出版日期2009-9-14