Anion-Responsive Tunable Bulk-Phase Homochirality and Luminescence of a Cationic Framework

作者:Manna Biplab; Joarder Biplab; Desai Aamod V; Karmakar Avishek; Ghosh Sujit K*
来源:Chemistry - A European Journal, 2014, 20(39): 12399-12404.
DOI:10.1002/chem.201403150

摘要

Reaction of a linear bi-chelating N-donor achiral ligand with Zn-II afforded a homochiral cationic framework with six-fold one-dimensional helical chains. The compound showed selective anion exchange behavior with interesting anion-responsive tunable bulk-phase homochirality. The cationic framework also presented anion-driven variable luminescence and sorption behavior.

  • 出版日期2014-9-22