科研之友
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摘要
A novel semi-flexible Cd(II)-MOF has been synthesized and characterized by variable temperature powder and single-crystal X-ray diffraction. The material displays an unusual combination of thermal expansion (TE) i.e. negative, zero and positive, which is an extremely rare finding, especially for metal- organic frameworks as a result of a combined stretching-tilting mechanism.
- 出版日期2014
