Nucleophilic Substitution Reaction at the Nitrogen of Arylsulfonamides with Phosphide Anion

作者:Yoshida Suguru; Igawa Kazunobu; Tomooka Katsuhiko*
来源:Journal of the American Chemical Society, 2012, 134(47): 19358-19361.
DOI:10.1021/ja309642r

摘要

A novel nucleophilic substitution reaction. at the nitrogen of arylsulfonamides by means, Of phosphide anions has been :described. This reaction allows for the efficient transformation of arylsulfonamides into synthetically valuable phosphamides, amines, and a variety of protected amines.

  • 出版日期2012-11-28