A non-interpenetrating lead-organic framework with large channels based on 1D tube-shaped SBUs

作者:Dai, Fangna*; Fan, Weidong; Yuan, Xue; Huang, Zhaodi; Wang, Yutong; Xin, Xuelian; Lin, Huan; Zhang, Liangliang; Wang, Rongming; Sun, Daofeng*
来源:Chemical communications, 2017, 53(42): 5694-5697.
DOI:10.1039/c7cc02134h

摘要

This work presents the construction of a porous lead-organic framework (UPC-10) with large channels of similar to 24 angstrom. UPC-10 shows efficient adsorption of I-2 and selective adsorption of some dyes containing the SO3- group. After the adsorption of dyes, UPC-10 exhibits a CO2 gas uptake ability. Furthermore, UPC-10 could be transformed into PbS in a H2S atmosphere, and the derived PbS manifests N-2 and CO2 uptake abilities.