Densities, Viscosities, Speeds of Sound, and Refractive Indices of Binary Mixtures of 2-Ethyl-1-hexanol with Benzene and Halobenzenes

作者：Bhatia Subhash C^*; Sangwan Ja**ir; Rani Ruman; Kiran Vijay

来源：International Journal of Thermophysics, 2013, 34(11): 2076-2088.

DOI：10.1007/s10765-013-1526-8

• Chlorobenzenes
• Density
• 2-Ethyl-1-hexanol
• Excess molar volume
• Molar refraction
• Refractive index
• Speed of sound
• Viscosity

Densities, , viscosities, , speeds of sound, , and refractive indices, , of binary liquid mixtures of 2-ethyl-1-hexanol with benzene, chlorobenzene, and bromobenzene have been measured over the entire range of composition at 298.15 K, 303.15 K, and 308.15 K and at atmospheric pressure. From the experimental data of the density, speed of sound, viscosity, and refractive index, the values of the excess molar volume, , isentropic compressibility, , and deviations in molar refraction, , have been calculated. The viscosity data have been correlated using McAllister's three-body interaction model at different temperatures. The calculated excess and deviation functions have been analyzed in terms of molecular interactions and structural effects.

• 出版日期2013-11