An Environmentally Benign and Cost-Effective Synthesis of Aminoferrocene and Aminoruthenocene

作者:Leonidova Anna; Joshi Tanmaya; Nipkow David; Frei Angelo; Penner Johanna Elena; Konatschnig Sandro; Patra Malay; Gasser Gilles*
来源:Organometallics, 2013, 32(6): 2037-2040.
DOI:10.1021/om400009g

摘要

An improved synthesis of aminoferrocene has been carried out that adheres with the basic green chemistry guidelines. Amination from aqueous NH3 as the nitrogen source, with the inexpensive CuI/Fe2O3 couple as cocatalyst in ethanolic solution, makes the process environmentally attractive as well as a viable alternative for all practical purposes. This procedure has also been applied to prepare aminoruthenocene, being reported for the first time.

  • 出版日期2013-3-25