摘要

A four-step synthesis of sterically demanding (R)-phenanthren-9-yl-[(S)-pyrrolidin-2-yl] methanol has been easily accomplished starting from L-proline in high diastereoselectivity. These compounds are potentially useful ligands in metal-catalyzed reactions and organocatalysts. Supplemental materials are available for this article. Go to the publisher%26apos;s online edition of Synthetic Communications (R) to view the free supplemental file.

  • 出版日期2013-2-1

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