A neutral Fe(III) compound exhibiting a two-step spin transition and dielectric anomalies

作者：Li Zhao Yang; Dai Jing Wei; Gagnon Kevin J; Cai Hong Ling; Yamamoto Takashi; Einaga Yasuaki; Zhao Han Hua; Kanegawa Shinji; Sato Osamu^*; Dunbar Kim R; Xiong Ren Gen

来源：Dalton Transactions, 2013, 42(41): 14685-14688.

DOI：10.1039/c3dt51554k

The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me)-H2O (1) was synthesized and characterized using powder/single-crystal X-ray diffraction, Mossbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound 1.

• 出版日期2013
• 单位东南大学