Detecting and Visualizing Reaction Intermediates of Anisotropic Nanoparticle Growth

作者:Chandra Kavita; Rugg Brandon K; Ratner Mark A; Wasielewski Michael R; Odom Teri W*
来源:Journal of the American Chemical Society, 2018, 140(9): 3219-3222.
DOI:10.1021/jacs.8b00124

摘要

This paper describes a correlative approach to detect, visualize, and characterize intermediate species during a seedless, anisotropic nanoparticle synthesis. Changes in radical concentration as a function of time were correlated in situ to the optical properties and morphology of the particles. Depending on type and concentration of reaction precursors, either one or two increases in radical production occurred, corresponding to initial particle formation and increased branch length, respectively. Thus, changes in radical intensity can be considered as an indicator of nanoparticle structure and properties.