科研之友
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摘要
This work studies the possibility of compounding natural fibres (flax) into engineering plastics (PA6 and PB6) and comparing the results with counterpart glass fibre composites. The problem in compounding is the difficulty to compound the fibres with such polymers of high melting temperatures without decomposing the natural fibre thermally. Preliminary experiments are tried to define the possible processing window using the kneader namely temperature, compounding time and shear rate. Fibre content is tried in range of 0-50 wt.% with 10% step. The mixing temperature covers the range around the melting temperature %26apos;Tm%26apos; [Tm-20, Tm+20]degrees C. The use of pre-melting temperature in compounding would utilise the energy evolving by fibres mutual rubbing. Compounding time is optimised at the minimum level. Shearing rate is tried at 25,50,75 and 100 rpm. Optimum conditions are defined to be 210-230 degrees C and 200-210 degrees C for PBT and PA6 respectively. Shearing rate is also defined to lie within 25-50 rpm. %26lt;br%26gt;Two different additives of non-organic mineral and organic phosphate flame retardants are tried with the prepared composites either alone or in combination with each other. The loading of flame retardants is limited to 20 wt.% in order to leave a space for natural fibres as well as the polymer and to keep in turn the overall composite mechanical properties. A mix of 1:1 ratio between the both types of retardants is needed to reach V0 flame retardation level. Mechanical properties are even improved 30% in E-modulus and 4% in strength with respect to composites without flame retardants. However, the injection moulding is reported to be difficult because of the high viscosity and the parameters should be optimised regarding the desired flame retardance level and the required mechanical properties as well as keeping the fibres not damaged.
- 出版日期2014-6
