Diazo Compounds in the Synthesis of O- and S-Containing Macroheterocycles

作者：Raskildina Gulnara Z; Zlotsky Simon S; Sultanova Rimma M^*

来源：Macroheterocycles, 2018, 11(2): 166-172.

DOI：10.6060/mhc170622s

• Carbenoids
• alpha-diazo carbonyl compounds
• O
• S-macroheterocycles
• cyclic acetals
• C-O and C-S insertions
• catalysis
• ylides

The review summarizes, systematizes and analyzes literature data of the synthesis of oxygen-and sulfur-containing macroheterocyclic systems using Rh and Cu-catalyzed reactions of diazocarbonyl compounds over the last 15-20 years. The review considers the intra- and intermolecular reactions of introduction of diazocarbonyl compounds, which are used in synthesis of practically important biologically active compounds, via the C-O and C-S bonds.

• 出版日期2018