Lanthanoid Induced C-F Activation of All Fluorine Atoms of One CF3 Group

作者：Deacon Glen B^*; Junk Peter C; Werner Daniel

来源：European Journal of Inorganic Chemistry, 2015, 2015(9): 1484-1489.

DOI：10.1002/ejic.201500137

• Rare earths
• Lanthanides
• Fluorine
• C-F activation

The lanthanum formamidinate complex [La(CF(3)Form)(3)] {CF(3)FormH = N, N'-bis(2-trifluoromethylphenyl)formamidine}, which has six La-F interactions in the solid-state structure, readily undergoes C-F activation of all fluorine atoms of one CF3 group to give LaF3, and two isomeric polytrifluoromethylphenyl-substituted polyamidines, one containing a 1,2,3,4-tetrahydroquinazoline heterocyclic core.

• 出版日期2015-3