科研之友
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摘要
A general and practical photoredox-promoted addition of nucleophiles to N-acylimines generated in situ from alpha-amidosulfides using Ru(bpy)(3)(PF6)(2) as the photocatalyst is reported. The broad scope of the reaction toward various nucleophiles and amidosulfide derivatives was explored. This novel protocol provides a rapid, mild, and efficient access to valuable alpha,alpha-disubstituted amines in respectable yields.
- 出版日期2016-3-18
