Novel dienone-phenol type rearrangement of 4,4-disubstituted cyclohexadienone system using thiosilane

作者：Wada Yasufumi; Otani Kouji; Endo Noriko; Kita Yasuyuki; Fujioka Hiromichi^*

来源：Chemical communications, 2010, 46(5): 797-799.

DOI：10.1039/b915294f

Thiosilane and a catalytic amount of a Bronsted acid mediate the novel domino-type rearrangement reaction of the 4,4-disubstituted cyclohexadienones to produce the 3,4-disubstituted benzenethioethers; the key step is 1,2-addition of thiosilane to dienone.

• 出版日期2010