Amino olefin nickel(I) and nickel(0) complexes as dehydrogenation catalysts for amine boranes

作者:Vogt Matthias; de Bruin Bas; Berke Heinz; Trincado Monica*; Gruetzmacher Hansjoerg
来源:Chemical Science, 2011, 2(4): 723-727.
DOI:10.1039/c0sc00483a

摘要

A rare paramagnetic organometallic nickel(I) olefin complex can be isolated using the ligand bis(5H-dibenzo[a,d]cyclohepten-5-yl)amine. This complex and related nickel(0) hydride complexes show very high catalytic activity in the dehydrogenation of dimethylamino borane with release of one equivalent of dihydrogen.

  • 出版日期2011