A new, efficient and recyclable [Ce(L-Pro)](2)(Oxa) heterogeneous catalyst used in the Kabachnik-Fields reaction

作者:da Silva Caren D G; Oliveira Aline R; Rocha Mariana P D; Katla Ramesh; Botero Eriton Rodrigo; da Silva Erica C; Domingues Nelson Luis C*
来源:RSC Advances, 2016, 6(32): 27213-27219.
DOI:10.1039/c5ra27064b

摘要

Herein we introduce a new catalyst for the Kabachnik-Fields reaction, [Ce(L-Pro)](2)(Oxa), using a very accessible, simple and efficient methodology for alpha-aminophosphonate synthesis using an aromatic aldehyde, an aromatic amine and diphenyl phosphite. This procedure was developed using a low catalyst loading of cerium(III) prolinate and it has allowed for the recycling of the catalyst.

  • 出版日期2016