Hemicarceplexes Modify the Solubility and Reduction Potentials of C-60

作者：Wong Tzu Huan; Chang Jia Cheng; Lai Chien Chen; Liu Yi Hung; Peng Shie Ming; Chiu Sheng Hsien^*

来源：Journal of Organic Chemistry, 2014, 79(8): 3581-3586.

DOI：10.1021/jo500405v

A highly stable C-60-incarcerated hemicarceplex, which retains its molecular integrity after heating at 523 K in air for at least 3 h, significantly increases the solubility of C-60 in nonpolar solvents and increases the reduction potentials of the entrapped fullerene. Modification with [(eta(5)-C5Me5)Ru-II](+) dramatically increases the solubility of this hemicarceplex in polar, protic solvents (e.g., MeOH).

• 出版日期2014-4-18
• 单位中国医科大学