As low as reasonably achievable catalyst loadings in the cross metathesis of olefins with ethyl acrylate

作者：Abbas Mudassar; Slugovc Christian^*

来源：Tetrahedron Letters, 2011, 52(20): 2560-2562.

DOI：10.1016/j.tetlet.2011.03.038

• Olefin metathesis
• Cross metathesis
• Ruthenium
• Acrylates

A series of ruthenium catalysts for olefin metathesis have been screened in the cross metathesis of 1,9-decadiene with ethyl acrylate. Under optimized reaction conditions a catalyst loading of only 100 ppm in respect to double bonds was sufficient for complete conversion of the diene.

• 出版日期2011-5-18