A room temperature cyanation of (hetero) aromatic chlorides by an air stable nickel(II) XantPhos precatalyst and Zn(CN)(2)

作者：Beattie D Dawson; Schareina Thomas; Beller Matthias^*

来源：Organic and Biomolecular Chemistry, 2017, 15(20): 4291-4294.

DOI：10.1039/c7ob00892a

A methodology for the synthesis of (hetero) aromatic nitriles from aryl chlorides at room temperature has been developed. This methodology uses an air and moisture stable nickel(II) XantPhos precatalyst and Zn(CN)(2) as the cyanide (CN-) source.

• 出版日期2017-5-28