A C-60-aryne building block: synthesis of a hybrid all-carbon nanostructure

作者：Garcia D; Rodriguez Perez L; Herranz M A; Pena D; Guitian E; Bailey S; Al Galiby Q; Noori M; Lambert C J; Perez D; Martin N

来源：Chemical Communications, 2016, 52(40): 6677-6680.

DOI：10.1039/c5cc10462a

The synthesis of a [60]fullerene-benzyne building block and its further chemical cycloaddition reaction with graphene has resulted in a new all-carbon hybrid material which has been characterized by TGA, FTIR and Raman spectroscopies, XPS as well as AFM and TEM. Based on computational studies, the formation of both [2+2] and [4+2] cycloadducts on the graphene surface is feasible.

• 出版日期2016