Diazonium Functionalization of Surfactant-Wrapped Chemically Converted Graphene Sheets

作者:Lomeda Jay R; Doyle Condell D; Kosynkin Dmitry V; Hwang Wen Fang; Tour James M*
来源:Journal of the American Chemical Society, 2008, 130(48): 16201-16206.
DOI:10.1021/ja806499w

摘要

Surfactant-wrapped chemically converted graphene sheets obtained from reduction of graphene oxide with hydrazine were functionlized by treatment with aryl diazonium salts. The nanosheets are characterized by X-ray photoelectron spectroscopy, attenuated total reflectance infrared spectroscopy, Raman spectroscopy, atomic force microscopy, and transmission electron microscopy. The resulting functionalized nanosheets disperse readily in polar aprotic solvents, allowing alternative avenues for simple incorporation into different polymer matrices.

  • 出版日期2008-12-3