A supramolecular synthon approach to aid the discovery of architectures sustained by C- H center dot center dot center dot M hydrogen bonds

作者：Siddiqui Kafeel Ahmad^*; Tiekink Edward R T

来源：Chemical Communications, 2013, 49(76): 8501-8503.

DOI：10.1039/c3cc44808h

Hydrogen bonding in the form of eight-membered {center dot center dot center dot HCNM}(2) synthons is identified in the crystal structures of nickel and copper complexes. These C-H center dot center dot center dot M interactions lead to the formation of well-defined zero-, one- and even two-dimensional supramolecular aggregation patterns.

• 出版日期2013