A highly efficient and reusable MCM-41-immobilized bipyridine copper(I) catalyst for the C-Se coupling of organoboronic acids with diaryl diselenides

作者：Zhao, Hong; Jiang, Yuanyuan; Chen, Qiurong; Cai, Mingzhong^*

来源：New Journal of Chemistry, 2015, 39(3): 2106-2115.

DOI：10.1039/c4nj01687d

• DIORGANYL SELENIDES
• HETEROGENEOUS CATALYSTS
• CONVENIENT SYNTHESIS
• RECYCLABLE CATALYST
• ARYL
• MCM-41
• BOND
• COMPLEXES
• CHEMISTRY
• ARYLATION

A highly efficient MCM-41-immobilized bipyridine copper(I) complex [MCM-41-bpy-CuI] was prepared from 4,4'-bis[3-(triethoxysilyl)propylaminomethyl]-2,2'-bipyridine via immobilization on the mesoporous material MCM-41, followed by reaction with CuI. In the presence of 5 mol% MCM-41-bpy-CuI, the cross-coupling reaction of organoboronic acids with diaryl diselenides proceeded smoothly in DMSO/H2O (2/1) at 110 degrees C under air to afford a variety of diorganyl selenides in good to excellent yields. This heterogeneous copper catalyst can be recovered and recycled by a simple filtration of the reaction solution and used for at least 10 consecutive trials without any decrease in activity.

• 出版日期2015
• 单位江西师范大学; 广东药科大学